Hi Jethro, g'day others
As stated - extremely dangerous in many many ways. Every metal in salt (acid) form is toxic. Even gold. Many precautions, proper workspace, fume hood, PPE etc.. really, no one should be playing with it, especially not a tato-tort.
Don't play with amalgam and mercury! Seek a proffessional! Do not attempt any of below - a lot of information is intentionally missing- I am not responsible if you attempt to throw acids and amalgam together. This is information about the science and safety, not the process.-
If you did ( or have) however, keep everything the amalgam touches, contained, and seperate from non-hg material. Store all the items you may have used, into an air tight container or ziplock bag, with a small amount of sulfur in bottom to soak up any possible vapours from natural heat. It will be contaminated forever, but can be reused for further amalgam works. Keep a confined workspace. Don't play with it any more, seek advice at gold meets.
Disposal-
Amalgam / Hg should always be contained within a larger vessel as you work- in case of spills and to stop it going everywhere on the floor. Google your closest heavy metal disposal recyclers to find where to dispose contaminated items. Last case scenario is bag and bin moist - still really not reccomended at all, dont be an enviro fiend!
An understanding-
As for the science, i'll keep it brief so no one can repeat the process from this text.
a lot is missing. As stated,
nitric and sulfuric can be used. Both very, very dangerous to work with, especially the
sulfuric, being extremely corrosive to our skin/body/eyes.
Both will dissolve the Hg from the amalgam, leaving the gold behind as a brown or grey-black powder. Gold decanted, filtered, washed and is smelted.
Hg recovery
The mercury now left in either acid, must be recovered by reactive metal, adding iron or aluminium. The mercury will cement or drop out. Mercury will not dissolve / amalgamate either of these two metals, so adding excess is never an issue and will recover 98% - 99% or so. Mercury is to be disposed to correct locations of heavy waste disposal- or stored in vessel, within another vessel, containing sulfur again for any spills / leaked vapours.
(Copper can be used, but aluminium and iron is cheaper, and you wont need to recover further metals after the drop. However if copper is somehow already in the solution, it will drop mecury+copper at the same time (messy/dirty mercury) when you add Al or Iron. If copper is in solution.. just keep adding more copper.)
--
Note to admins - Hello! If it's too much - delete. No one has enough info there to copy process, but totally understand as the 'been there done that' issues prior
It's more a safety note, than an instructional note. Only those who know the safety, will understand the text. I have tripple checked, but see how it goes.